Only eighteen years of age when she was crowned Miss Universe, Rivera is one of the youngest women to win the title.

She is also the first winner from Puerto Rico to have noticeable mixed (African and Indigenous) heritage features, different from her four predecessors (Marisol Malaret, Deborah Carthy-Deu, Dayanara Torres, and Denise Quiñones) that have distinctly European features.

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Rivera was the third consecutive delegate from Puerto Rico to make the Top 5 at Miss Universe, after Alba Reyes placed 2nd Runner-Up in 2004 and Cynthia Olavarría placed 1st Runner-Up in 2005.

Rivera's win came only five years after Denise Quiñones, the most recent winner from Puerto Rico, won the crown.

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At the Miss Universe 2007 pageant she passed her crown to Riyo Mori of Japan in Mexico City, Mexico on May 28, 2007.